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Materials for electrochemical capacitors

Abstract

Electrochemical capacitors, also called supercapacitors, store energy using either ion adsorption (electrochemical double layer capacitors) or fast surface redox reactions (pseudo-capacitors). They can complement or replace batteries in electrical energy storage and harvesting applications, when high power delivery or uptake is needed. A notable improvement in performance has been achieved through recent advances in understanding charge storage mechanisms and the development of advanced nanostructured materials. The discovery that ion desolvation occurs in pores smaller than the solvated ions has led to higher capacitance for electrochemical double layer capacitors using carbon electrodes with subnanometre pores, and opened the door to designing high-energy density devices using a variety of electrolytes. Combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries. The use of carbon nanotubes has further advanced micro-electrochemical capacitors, enabling flexible and adaptable devices to be made. Mathematical modelling and simulation will be the key to success in designing tomorrow's high-energy and high-power devices.

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Figure 1: Specific power against specific energy, also called a Ragone plot, for various electrical energy storage devices.
Figure 2: Carbon structures used as active materials for double layer capacitors.
Figure 3: Electrochemical capacitors.
Figure 4: Specific capacitance normalized by SSA as a function of pore size for different carbon samples.
Figure 5: Normalized capacitance change as a function of the pore size of carbon-derived-carbide samples.
Figure 6: Cyclic voltammetry.
Figure 7: Possible strategies to improve both energy and power densities for electrochemical capacitors.

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Acknowledgements

We thank our students and collaborators, including J. Chmiola, C. Portet, R. Dash and G. Yushin (Drexel University), P. L. Taberna and C. Largeot (Université Paul Sabatier), and J. E. Fischer (University of Pennsylvania) for experimental help and discussions, H. Burnside (Drexel University) for editing the manuscript and S. Cassou (Toulouse) for help with illustrations. This work was partially funded through the Department of Energy, Office of Basic Energy Science, grant DE-FG01-05ER05-01, and through the Délégation Générale pour l'Armement.

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Simon, P., Gogotsi, Y. Materials for electrochemical capacitors. Nature Mater 7, 845–854 (2008). https://doi.org/10.1038/nmat2297

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